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Organic Chemistry

Aldehydes, Ketones & Acids

Browse 60 questions on Aldehydes, Ketones & Acids. Click on any question to view the detailed answer and explanation.

What is the common name of benzene-1,2-dicarbaldehyde?

Nomenclature

What is the IUPAC name of CH2=CHCHO\text{CH}_2=\text{CHCHO} (Acrolein)?

Nomenclature

What is the common name of 1-Phenylpropan-1-one?

Nomenclature

What is the hybridization of the carbonyl carbon atom?

Structure

Why is the carbonyl group polar?

Structure

Name the reaction: RCOCl+H2Pd-BaSO4RCHO\text{RCOCl} + \text{H}_2 \xrightarrow{\text{Pd-BaSO}_4} \text{RCHO}

Preparation

What reagents are used in the Stephen reaction to convert nitriles to aldehydes?

Preparation

What specific reagent selectively reduces nitriles and esters to aldehydes?

Preparation

Name the reaction that converts toluene to benzaldehyde using CrO2Cl2\text{CrO}_2\text{Cl}_2 andCS2\text{CS}_2 followed by hydrolysis.

Preparation

In the Gatterman-Koch reaction, what reagents convert benzene to benzaldehyde?

Preparation

Which reagent is used to prepare ketones from acyl chlorides ( 2R-COCl+R2Cd2R-CO-R+CdCl22\text{R-COCl} + \text{R}_2\text{Cd} \to 2\text{R-CO-R} + \text{CdCl}_2 )?

Preparation

What is the product of the hydration of ethyne in the presence of H2SO4\text{H}_2\text{SO}_4 andHgSO4\text{HgSO}_4?

Preparation

Why is the boiling point of aldehydes/ketones lower than alcohols of similar molecular mass?

Physical Properties

Why are aldehydes generally more reactive than ketones in nucleophilic addition reactions?

Reactivity

Why is benzaldehyde less reactive than propanal in nucleophilic addition?

Reactivity

What forms when aldehydes react with HCN in the presence of a base?

Chemical Reactions

Which reagent is added to aldehydes/ketones to purify them as a crystalline solid?

Chemical Reactions

What is the product formed when an aldehyde reacts with one equivalent of alcohol in the presence of dry HCl?

Chemical Reactions

What is the final product when a ketone reacts with ethylene glycol in the presence of dry HCl?

Chemical Reactions

What is the product of the reaction between a carbonyl compound and hydroxylamine ( NH2OH\text{NH}_2\text{OH} )?

Chemical Reactions

What is the product of the reaction between a carbonyl compound and hydrazine ( NH2NH2\text{NH}_2\text{NH}_2 )?

Chemical Reactions

Which reagent is used to characterize aldehydes and ketones by forming a yellow/orange/red precipitate?

Chemical Reactions

Name the reduction: Carbonyl group CH2\to \text{CH}_2 using Zinc amalgam ( Zn-Hg\text{Zn-Hg} ) and conc. HCl\text{HCl} .

Reduction

Name the reduction: Carbonyl group CH2\to \text{CH}_2 using Hydrazine followed by heating with KOH in ethylene glycol.

Reduction

What is Tollens' reagent?

Oxidation

What is observed when an aldehyde is heated with Tollens' reagent?

Oxidation

What does Fehling's solution test for?

Oxidation

What is the visible result of a positive Fehling's test?

Oxidation

Which specific structural unit is required for a compound to undergo the Haloform reaction?

Oxidation

Does a carbon-carbon double bond get oxidized during the Haloform reaction?

Oxidation

What is the condition for an aldehyde or ketone to undergo Aldol condensation?

Alpha-Hydrogen

What are the reagents for Aldol condensation?

Alpha-Hydrogen

What is the functional group present in an "Aldol"?

Alpha-Hydrogen

What is the final product of Aldol condensation after heating (dehydration)?

Alpha-Hydrogen

What is Cross Aldol Condensation?

Alpha-Hydrogen

Name the reaction: Disproportionation of aldehydes with NO α\alpha -hydrogen in concentrated alkali.

Alpha-Hydrogen

What are the products of the Cannizzaro reaction of Formaldehyde?

Alpha-Hydrogen

Is the carbonyl group in aromatic aldehydes/ketones ortho/para or meta directing?

Electrophilic Subst.

What is the common name of Hexanedioic acid?

Carboxylic Acids

What is the IUPAC name of Oxalic acid?

Carboxylic Acids

Why do carboxylic acids exist as dimers in vapour phase or aprotic solvents?

Carboxylic Acids

How does boiling point of carboxylic acids compare to alcohols of similar mass?

Carboxylic Acids

Compare the acidity of carboxylic acids and phenols.

Acidity

Why is the carboxylate ion more stable than the phenoxide ion?

Acidity

How do Electron Withdrawing Groups (EWG) affect the acidity of carboxylic acids?

Acidity

Arrange in decreasing acidity: CF3COOH,CCl3COOH,CHCl2COOH,NO2CH2COOH\text{CF}_3\text{COOH}, \text{CCl}_3\text{COOH}, \text{CHCl}_2\text{COOH}, \text{NO}_2\text{CH}_2\text{COOH} .

Acidity

What is the product of vigorous oxidation of alkylbenzenes with chromic acid or KMnO4\text{KMnO}_4 ?

Preparation

Reaction of Grignard reagent ( RMgX\text{RMgX} ) with Dry Ice ( CO2\text{CO}_2 ) followed by hydrolysis gives?

Preparation

What reagent is used for the decarboxylation of sodium salts of carboxylic acids?

Reactions

Name the reaction: Halogenation of carboxylic acids at α\alpha -position using X2\text{X}_2 /Red Phosphorus.

Reactions

What is the product of heating a carboxylic acid with P2O5\text{P}_2\text{O}_5 orH2SO4\text{H}_2\text{SO}_4?

Reactions

What is the mechanism type for the esterification of carboxylic acids?

Reactions

Why is SOCl2\text{SOCl}_2 preferred overPCl5\text{PCl}_5/ PCl3\text{PCl}_3 for preparing acid chlorides?

Reactions

Product of heating Ammonium benzoate?

Reactions

Product of strong heating of Ammonium phthalate?

Reactions

Reagent used to reduce Carboxylic acids to Primary Alcohols?

Reactions

Does Sodium Borohydride ( NaBH4\text{NaBH}_4 ) reduce the carboxyl group?

Reactions

What is Formalin?

Uses

What is the industrial use of Hexanedioic acid?

Uses

Which carboxylic acid salt is commonly used as a food preservative?

Uses