Questions/Amines/How can a mixture of...
Tests for AminesAmines

How can a mixture of 1,2,and 31^\circ, 2^\circ, \text{and } 3^\circ amines be separated chemically?

Expert Answer

Using the Hinsberg Method. 1. React mixture with PhSO2ClPhSO_2Cl . 2. Acidify: 11^\circ derivative precipitates (was soluble in base). 3. Filter: 22^\circ derivative is solid (insoluble in base/acid). 4. Filtrate: Contains 33^\circ amine (didn't react, soluble in acid).

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