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Electrophilic SubstitutionAmines

How does the product of Aniline bromination differ in CS2CS_2 (non-polar) versus Aqueous (polar) medium?

Expert Answer

In aqueous medium, it gives 2,4,6-Tribromoaniline (white ppt). In non-polar CS2CS_2 , the low polarity suppresses the activation, yielding mono-substituted 4-Bromoaniline (major) and 2-Bromoaniline

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