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Physical Chemistry

Atomic Structure

Browse 60 questions on Atomic Structure. Click on any question to view the detailed answer and explanation.

Who discovered the electron and determined its charge-to-mass ratio ( e/me/m )?

Sub-atomic Particles

What is the value of the charge-to-mass ratio ( e/me/m ) for an electron?

Sub-atomic Particles

Which experiment was used to determine the charge on an electron?

Sub-atomic Particles

How do cathode rays behave in the absence of electrical or magnetic fields?

Sub-atomic Particles

Does the nature of cathode rays depend on the gas present in the tube?

Sub-atomic Particles

Unlike cathode rays, on what factor do positively charged canal rays depend?

Sub-atomic Particles

What was the main conclusion of Rutherford's α\alpha -particle scattering experiment regarding the atom's structure?

Atomic Models

What is the approximate relationship between the radius of the atom and the radius of the nucleus?

Atomic Models

Define Isotopes.

Atomic Terms

Define Isobars.

Atomic Terms

If an ion has mass number 56, 3 units of positive charge, and 30.4% more neutrons than electrons, what is the symbol?

Atomic Terms

What is the relationship between frequency ( ν\nu ), wavelength ( λ\lambda ), and speed of light ( cc )?

EM Radiation

What is the value of Planck's constant ( hh )?

EM Radiation

According to Planck, energy ( EE ) of a quantum of radiation is given by which formula?

EM Radiation

What is the threshold frequency ( ν0\nu_0 )?

Photoelectric Effect

Write Einstein's photoelectric equation relating kinetic energy of ejected electron to incident frequency.

Photoelectric Effect

Does the kinetic energy of ejected photoelectrons depend on the brightness (intensity) of light?

Photoelectric Effect

What type of spectrum is observed when white light is passed through an absorbing sample?

Atomic Spectra

What is the formula for the wavenumber ( νˉ\bar{\nu} ) of lines in the hydrogen spectrum (Rydberg formula)?

Hydrogen Spectrum

Which series of the hydrogen spectrum appears in the visible region?

Hydrogen Spectrum

Which series of the hydrogen spectrum appears in the ultraviolet region?

Hydrogen Spectrum

What are the values of n1n_1 and n2n_2 for the Paschen series?

Hydrogen Spectrum

What is the quantization condition for angular momentum in Bohr's model?

Bohr's Model

What is the formula for the radius of the nn th orbit in a hydrogen-like species?

Bohr's Model

What is the energy of an electron in the nn th orbit of a Hydrogen atom (in Joules)?

Bohr's Model

What does the negative sign in the energy expression of an electron signify?

Bohr's Model

What is the energy expression for hydrogen-like ions (He+^+ , Li2+ ^{2+})?

Bohr's Model

Calculate the radius of the first orbit of He+He^+ ( n=1,Z=2n=1, Z=2 ).

Bohr's Model

What are two major limitations of Bohr's model?

Bohr's Model

Write the de Broglie equation relating wavelength and momentum.

Dual Nature

Why is the wave nature of macroscopic objects not observable?

Dual Nature

State the mathematical expression for Heisenberg's Uncertainty Principle.

Uncertainty Principle

What does Heisenberg's principle imply about the "trajectory" of an electron?

Uncertainty Principle

"In the Quantum Mechanical model, what does the square of the wave function ( ψ2|\psi|^2 ) represent?"

Quantum Mechanical Model

What information does the Principal Quantum Number ( nn ) provide?

Quantum Numbers

What does the Azimuthal Quantum Number ( ll ) define?

Quantum Numbers

For a given value of nn , what are the possible values of ll ?

Quantum Numbers

Which orbital corresponds to n=3n=3 and l=2l=2 ?

Quantum Numbers

What is the total number of orbitals in a shell with principal quantum number nn ?

Quantum Numbers

What does the Magnetic Quantum Number ( mlm_l ) designate?

Quantum Numbers

How many orbitals are there in a dd -subshell ( l=2l=2 )?

Quantum Numbers

How many nodes (radial nodes) does an orbital have in general?

Orbitals

How many angular nodes does a pp orbital have?

Orbitals

What is the shape of an ss -orbital?

Shapes of Orbitals

What is the shape of a pp -orbital?

Shapes of Orbitals

Which dd -orbital has a shape different from the other four (doughnut shape)?

Shapes of Orbitals

State the Aufbau Principle.

Electronic Configuration

State Pauli's Exclusion Principle.

Electronic Configuration

State Hund's Rule of Maximum Multiplicity.

Electronic Configuration

Which rule determines the energy order of orbitals in multi-electron atoms?

Electronic Configuration

In the case of H-atom, what determines the energy of the orbital?

Electronic Configuration

Why is the electronic configuration of Chromium (Cr) 3d54s13d^5 4s^1 instead of 3d44s23d^4 4s^2 ?

Electronic Configuration

What is the electronic configuration of Copper (Cu, Z=29)?

Electronic Configuration

What is Exchange Energy?

Electronic Configuration

What is the maximum number of electrons that can be accommodated in a subshell with azimuthal quantum number ll ?

Electronic Configuration

How many electrons can be accommodated in the shell with n=4n=4 ?

Electronic Configuration

Which orbital is filled after 4p4p ?

Electronic Configuration

What is the splitting of spectral lines in a magnetic field called?

Effects

What is the splitting of spectral lines in an electric field called?

Effects

What are the "core electrons"?

General