Questions/D & F Block/Why is the highest o...
Ionisation Enthalpy & Oxidation StatesD & F Block

Why is the highest oxidation state of Mn +7 in oxides ( Mn2O7Mn_2O_7 ) but only +4 in fluorides ( MnF4MnF_4 )?

Expert Answer

Oxygen can form multiple bonds ( pπdπp\pi-d\pi ) with the metal, stabilizing high oxidation states, whereas fluorine can only form single bonds.

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