Questions/Electrochemistry/In a Daniell cell, w...
Galvanic CellsElectrochemistry

In a Daniell cell, what happens to the current flow if an external opposing potential (EextE_{ext}) slightly greater than 1.1 V is applied?.

Expert Answer

The current flows in the opposite direction (from Zn to Cu), and the cell functions as an electrolytic cell (non-spontaneous reaction occurs). Now reduction happens in Zn half cell and oxidation in Cu half cell.

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