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Inorganic Chemistry

Most Important Inorganic Trends

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Ionic Size: Mg2+<Na+<F<O2Mg^{2+} < Na^{+} < F^{-} < O^{2-}

Atomic & Periodic Properties

Acidity of Oxides: Na2O2<MgO<ZnO<P2O5Na_{2}O_{2} < MgO < ZnO < P_{2}O_{5}

Acidity & Basicity

First Ionisation Energy: Na<Al<Mg<SiNa < Al < Mg < Si

Atomic & Periodic Properties

Bond Length: N2(Triple)<O2(Double)<F2(Single)<Cl2N_{2} (Triple) < O_{2} (Double) < F_{2} (Single) < Cl_{2}

Chemical Bonding

Ionic Size: Ca2+<K+<Ar<Cl<S2Ca^{2+} < K^{+} < Ar < Cl^{-} < S^{2-}

Atomic & Periodic Properties

Acid Strength: HClO<HClO2<HClO3<HClO4HClO < HClO_{2} < HClO_{3} < HClO_{4}

Acidity & Basicity

Bond Strength: HI<HBr<HCl<HFHI < HBr < HCl < HF

Chemical Bonding

Oxidation state: HI(1)<I2(0)<ICl(+1)<HIO4(+7)HI (-1) < I_{2} (0) < ICl (+1) < HIO_{4} (+7)

Redox & Electrochemistry

Thermal Stability: HClO<HClO2<HClO3<HClO4HClO < HClO_{2} < HClO_{3} < HClO_{4}

Chemical Bonding

Bond Enthalpy: F2<Cl2<O2<N2F_{2} < Cl_{2} < O_{2} < N_{2}

Chemical Bonding

Acidic Character: K2O<MgO<CO2<SO3K_2O < MgO < CO_{2} < SO_{3}

Acidity & Basicity

Ionic Size: Mg2+<Na+<F<O2<N3Mg^{2+} < Na^{+} < F^{-} < O^{2-} < N^{3-}

Atomic & Periodic Properties

Basic Character: NiO<MgO<SrO<K2O<Cs2ONiO < MgO < SrO < K_{2}O < Cs_{2}O

Acidity & Basicity

Extent of Hydrolysis: CCl4<MgCl2<AlCl3<SiCl4<PCl5CCl_{4} < MgCl_{2} < AlCl_{3} < SiCl_{4} < PCl_{5}

Stability & Reactivity

H Bonding Strength: S<N<Cl<O<FS < N < Cl < O < F

Atomic & Periodic Properties

Hydrated ionic Radius: Cs+<Rb+<K+<Na+<Li+Cs^{+} < Rb^{+} < K^{+} < Na^{+} < Li^{+}

Solubility & Hydration

Molar Conductivity in water: Li+<Na+<K+<Rb+<Cs+Li^{+} < Na^{+} < K^{+} < Rb^{+} < Cs^{+}

Physical Properties

Reactivity with water: Li<Na<K<Rb<CsLi < Na < K < Rb < Cs

Stability & Reactivity

Reactivity with Hydrogen: Li>Na>K>Rb>CsLi > Na > K > Rb > Cs

Redox & Electrochemistry

Melting Point (Alkali Metals): Li>Na>K>Rb>CsLi > Na > K > Rb > Cs

Physical Properties

Basic Nature (Alkali Hydroxides): LiOH<NaOH<KOH<RbOH<CsOHLiOH < NaOH < KOH < RbOH < CsOH

Acidity & Basicity

Thermal Stability: LiOH<NaOH<KOH<RbOH<CsOHLiOH < NaOH < KOH < RbOH < CsOH

Stability & Reactivity

Covalent Character: LiCl<LiBr<LiILiCl < LiBr < LiI

Chemical Bonding

Ionic Character: BeCl2<MgCl2<CaCl2<SrCl2<BaCl2BeCl_{2} < MgCl_{2} < CaCl_{2} < SrCl_{2} < BaCl_{2}

Chemical Bonding

Solubility: MgCO3>CaCO3>SrCO3>BaCO3MgCO_{3} > CaCO_{3} > SrCO_{3} > BaCO_{3}

Solubility & Hydration

Solubility: MgF2<CaF2<SrF2<BaF2MgF_{2} < CaF_{2} < SrF_{2} < BaF_{2} (Note: BeF2BeF_2 is highly soluble)

Solubility & Hydration

Solubility: Mg(OH)2<Ca(OH)2<Sr(OH)2<Ba(OH)2Mg(OH)_{2} < Ca(OH)_{2} < Sr(OH)_{2} < Ba(OH)_{2}

Solubility & Hydration

Basicity: Be(OH)2<Mg(OH)2<Ca(OH)2<Ba(OH)2Be(OH)_{2} < Mg(OH)_{2} < Ca(OH)_{2} < Ba(OH)_{2}

Acidity & Basicity

Hydration Enthalpy (Group 2): Be2+>Mg2+>Ca2+>Sr2+>Ba2+Be^{2+} > Mg^{2+} > Ca^{2+} > Sr^{2+} > Ba^{2+}

Solubility & Hydration

Reactivity with water: Be<Mg<Ca<Sr<BaBe < Mg < Ca < Sr < Ba

Stability & Reactivity

Reactivity. towards Air: Be<Mg<Ca<Sr<BaBe < Mg < Ca < Sr < Ba

Stability & Reactivity

Solubility (Group 2 Sulphates): BeSO4>MgSO4>CaSO4>SrSO4>BaSO4BeSO_{4} > MgSO_{4} > CaSO_{4} > SrSO_{4} > BaSO_{4}

Solubility & Hydration

Ionic Character: BCl3<AlCl3<GaCl3BCl_{3} < AlCl_{3} < GaCl_{3}

Chemical Bonding

Lewis Acid Strength (Boron Halides): BF3<BCl3<BBr3<BI3BF_{3} < BCl_{3} < BBr_{3} < BI_{3}

Acidity & Basicity

Lewis Acid Strength (Group 13): AlCl3>GaCl3>InCl3AlCl_{3} > GaCl_{3} > InCl_{3}

Acidity & Basicity

Reducing Power: GeCl2>SnCl2>PbCl2GeCl_{2} > SnCl_{2} > PbCl_{2}

Redox & Electrochemistry

Oxidizing Power: GeCl4<SnCl4<PbCl4GeCl_{4} < SnCl_{4} < PbCl_{4}

Redox & Electrochemistry

Catenation Tendency: C>Si>GeSn>PbC > Si > Ge \approx Sn > Pb

Chemical Bonding

Basicity: NH3>PH3>AsH3>SbH3>BiH3NH_{3} > PH_{3} > AsH_{3} > SbH_{3} > BiH_{3}

Acidity & Basicity

Thermal Stability: NH3>PH3>AsH3>SbH3>BiH3NH_{3} > PH_{3} > AsH_{3} > SbH_{3} > BiH_{3}

Stability & Reactivity

Acidic Strength: HNO3>H3PO4>H3AsO4>H3SbO4HNO_{3} > H_{3}PO_{4} > H_{3}AsO_{4} > H_{3}SbO_{4}

Acidity & Basicity

Solubility in water: HNO3>H3PO4>H3AsO4HNO_{3} > H_{3}PO_{4} > H_{3}AsO_{4}

Solubility & Hydration

Stability of +5 Oxidation State: P>As>Sb>BiP > As > Sb > Bi (Due to Inert Pair Effect)

Stability & Reactivity

Extent of Hydrolysis: NCl3NCl_3 (Explosive), PCl3PCl_3 (Complete), AsCl3AsCl_3 & SbCl3SbCl_3 (Partial), BiCl3BiCl_3 (Partial)

Stability & Reactivity

Stability of Hydrides: H2O>H2S>H2Se>H2TeH_{2}O > H_{2}S > H_{2}Se > H_{2}Te

Stability & Reactivity

Poisonous Nature: H2O<H2S<H2Se<H2TeH_{2}O < H_{2}S < H_{2}Se < H_{2}Te

Stability & Reactivity

Acidity: H2O<H2S<H2Se<H2TeH_{2}O < H_{2}S < H_{2}Se < H_{2}Te

Acidity & Basicity

Acidic Strength: H2SO3>H2SeO3>H2TeO3H_{2}SO_{3} > H_{2}SeO_{3} > H_{2}TeO_{3}

Acidity & Basicity

Stability: H2SO3>H2SeO3>H2TeO3H_{2}SO_{3} > H_{2}SeO_{3} > H_{2}TeO_{3}

Stability & Reactivity

Acidic Strength: H2SO4>H2SeO4>H6TeO6H_{2}SO_{4} > H_{2}SeO_{4} > H_{6}TeO_{6}

Acidity & Basicity

Oxidizing Power: H2SO4<H2SeO4<H6TeO6H_{2}SO_{4} < H_{2}SeO_{4} < H_{6}TeO_{6}

Redox & Electrochemistry

Electron Affinity (Halogens): I<Br<F<ClI < Br < F < Cl (Note: F < Cl due to repulsion)

Atomic & Periodic Properties

Reducing Power : HF<HCl<HBr<HIHF < HCl < HBr < HI

Acidity & Basicity

Affinity for Hydrogen: F2>Cl2>Br2>I2F_{2} > Cl_{2} > Br_{2} > I_{2}

Redox & Electrochemistry

Acidity: HF<HCl<HBr<HIHF < HCl < HBr < HI

Acidity & Basicity

MP: HCl<HBr<HI<HFHCl < HBr < HI < HF (HF highest due to H-bonding)

Physical Properties

BP: HCl<HBr<HI<HFHCl < HBr < HI < HF

Physical Properties

Acidity: HIO3<HBrO3<HClO3HIO_{3} < HBrO_{3} < HClO_{3}

Acidity & Basicity

Covalent Character: TiCl2<TiCl3<TiCl4TiCl_{2} < TiCl_{3} < TiCl_{4}

Chemical Bonding

Magnetic Moment: Zn2+(0)<Cu2+<Ni2+<Co2+<Fe2+<Mn2+Zn^{2+} (0) < Cu^{2+} < Ni^{2+} < Co^{2+} < Fe^{2+} < Mn^{2+}

Atomic & Periodic Properties

Ionic Character: VCl2>VCl3>VCl4VCl_{2} > VCl_{3} > VCl_{4}

Chemical Bonding

Electropositivity: Hg<Cu<Na<Li<CsHg < Cu < Na < Li < Cs

Redox & Electrochemistry

Density: Al<Fe<Pb<AuAl < Fe < Pb < Au

Atomic & Periodic Properties

Basicity: Li2O>BeO>B2O3>CO2Li_{2}O > BeO > B_{2}O_{3} > CO_{2}

Acidity & Basicity

Electronegativity: As<PH<S<C<ClAs < P \approx H < S < C < Cl

Atomic & Periodic Properties

Ionisation Energy: O<N<FO < N < F (N > O due to half-filled p-orbital)

Atomic & Periodic Properties

Atomic Size: O<C<S<SeO < C < S < Se

Atomic & Periodic Properties

Acidity: HOCl>HOBr>HOIHOCl > HOBr > HOI

Acidity & Basicity

Density: H2<NH3<O2<H2S<CO2H_{2} < NH_{3} < O_{2} < H_{2}S < CO_{2}

Physical Properties

Thermal Stability: HF>HCl>HBr>HIHF > HCl > HBr > HI

Stability & Reactivity

Bond Enthalpy: I2<F2<Br2<Cl2I_{2} < F_{2} < Br_{2} < Cl_{2} (F2 is low due to repulsion)

Chemical Bonding

Melting Point: CaI2<CaBr2<CaCl2<CaF2CaI_{2} < CaBr_{2} < CaCl_{2} < CaF_{2}

Physical Properties

Oxidizing Power: O>S>Se>TeO > S > Se > Te

Redox & Electrochemistry

Oxidizing Power: F2>Cl2>Br2>I2F_{2} > Cl_{2} > Br_{2} > I_{2}

Redox & Electrochemistry

Atomic Size: B<Be<Li<NaB < Be < Li < Na

Atomic & Periodic Properties

Bond Length: NN<OO<FFN-N < O-O < F-F (Usually H-H shortest, but among these: O-O < N-N < F-F is wrong. N-N 1.45, O-O 1.48, F-F 1.42. F-F is usually sho...

Chemical Bonding

Stability of Hydrides: LiH>NaH>KH>RbH>CsHLiH > NaH > KH > RbH > CsH

Stability & Reactivity

pH of Aqueous Solution: NaCl(7)>MgCl2>AlCl3NaCl (7) > MgCl_{2} > AlCl_{3}

Acidity & Basicity

Acidity: MgO<Al2O3<SiO2<P4O10MgO < Al_{2}O_{3} < SiO_{2} < P_{4}O_{10}

Acidity & Basicity

Nucleophilicity (in Polar Protic Solvent): F<Cl<Br<IF^{-} < Cl^{-} < Br^{-} < I^{-}

Atomic & Periodic Properties

Basicity: F<OH<NH2<CH3F^{-} < OH^{-} < NH_{2}^{-} < CH_{3}^{-}

Acidity & Basicity

Boiling Point: PH3<AsH3<NH3<SbH3<BiH3PH_{3} < AsH_{3} < NH_{3} < SbH_{3} < BiH_{3} (Note: NH3NH_3 is high due to H-bond)

Physical Properties

Ionization Energy: B<C<O<N<F<NeB < C < O < N < F < Ne

Atomic & Periodic Properties

Thermal Stability: BeCO3<MgCO3<CaCO3<SrCO3<BaCO3BeCO_{3} < MgCO_{3} < CaCO_{3} < SrCO_{3} < BaCO_{3}

Stability & Reactivity

Paramagnetism (Elements): OO (Paramagnetic), NN (Paramagnetic), Ca,AlCa, Al (Paramagnetic as metals? Al is para, Ca is para).

Atomic & Periodic Properties

Ionic Character: LiBr<NaBr<KBr<RbBr<CsBrLiBr < NaBr < KBr < RbBr < CsBr

Chemical Bonding

Hydration Energy: Be2+>Mg2+>Ca2+>Sr2+>Ba2+Be^{2+} > Mg^{2+} > Ca^{2+} > Sr^{2+} > Ba^{2+}

Solubility & Hydration

Bond Angle: NH3(107)>PH3(93)>AsH3>SbH3NH_{3} (107^{\circ}) > PH_{3} (93^{\circ}) > AsH_{3} > SbH_{3}

Chemical Bonding

Bond Angle: AsF3<PF3<NF3AsF_{3} < PF_{3} < NF_{3} (Trend is usually PF3<PCl3PF_3 < PCl_3 )

Chemical Bonding

Bond Angle: H2O(104.5)>H2S(92)>H2Se>H2TeH_{2}O (104.5^{\circ}) > H_{2}S (92^{\circ}) > H_{2}Se > H_{2}Te

Chemical Bonding

Bond Angle: NF3<NCl3NF_{3} < NCl_{3}

Chemical Bonding

Bond Angle: NO2<NO2<NO2+NO_{2}^{-} < NO_{2} < NO_{2}^{+}

Chemical Bonding

Bond Angle: NF3<NH3NF_{3} < NH_{3}

Chemical Bonding

Bond Angle: PH3<PF3PH_{3} < PF_{3}

Chemical Bonding

Size: O<O<O2O < O^{-} < O^{2-}

Atomic & Periodic Properties

Dipole Moment: CH3Cl>CH2Cl2>CHCl3>CCl4CH_{3}Cl > CH_{2}Cl_{2} > CHCl_{3} > CCl_{4}

Chemical Bonding

Ionic Nature: MCl>MCl2>MCl3MCl > MCl_{2} > MCl_{3}

Chemical Bonding

Strength of H-Bonding: S<Cl<N<O<FS < Cl < N < O < F

Atomic & Periodic Properties

NO Bond Length: NO2+<NO2<NO2<NO3NO_{2}^{+} < NO_{2} < NO_{2}^{-} < NO_{3}^{-}

Chemical Bonding

Bond Order: O22(1)<O2(1.5)<O2(2)<O2+(2.5)O_{2}^{2-} (1) < O_{2}^{-} (1.5) < O_{2} (2) < O_{2}^{+} (2.5)

Chemical Bonding