Preparation reactions of Alkanes Introduction, Preparation reactions of Alkanes: Reduction of alkyl halides, Clemmensen & Wolff Kishner reduction, reduction of acids, carbonyl compounds & alcohols, hydrogenation of alkenes & alkynes, from Grignard Reagent, soda -lime decarboxylation, Wurtz Reaction, Corey house synthesis, Frankland reaction
Halogenation of alkanes Kolbe's Electrolysis, Physical Properties of alkanes, halogenation of alkanes, Reactivity - Selectivity principle, isomerisation
Problem Practice on Reactions of Alkanes Problem Practice on Reactions of Alkanes
Introduction to Alkenes & Alkynes Classification of Alkenes & alkynes, Nomenclature of Alkenes & alkynes, Degree of Unsaturation. Heat of hydrogenation, Saytzeff's Rule, Stability of cycloalkenes, Bredt's Rule
Preparation of alkenes & Alkynes Using Hydrogenation of alkynes using Lindlar's catalyst, Birch Reduction, Dehydrohalogenation of alkyl halides, Dehydration of alcohols, Kolbe's electrolysis, Hydrolysis of carbides
Chemical reactions of alkenes & alkynes - I Electrophilic addition reaction mechanism. Hydration, halohydrin formation, addition of HX, Epoxidation, Dihydroxylation, addition of halogen. Bromine-water Test for unsaturation. Markovnikov's rule
Chemical reactions of alkenes & alkynes - II Addition of HBr with peroxide (Kharasch effect). Acid-catalysed hydration. Oxymercuration- Demercuration, Hydroboration- Oxidation. Hydration of alkynes, Catalylic Hydrogenation,
Chemical reactions of alkenes & alkynes - III Allylic halogenation, Stereochemistry of halogen-addition across carbon double bond, Simmons-Smith reaction, epoxidation of alkenes & opening of epoxides.
Chemical reactions of alkenes & alkynes - IV Reaction with KMnO4 and OsO4, Ozonolysis, Distinction between alkene and alkyne
Problem Practice on Reactions of Alkenes & Alkynes Problem Practice on Reactions of Alkenes & Alkynes