A dipeptide, "x" on complete hydrolysis gives "y" and "z". "y" on treatment with aq. HNO2 produces lactic acid. On the…
Biomolecules · Class 12 · JEE Main Previous Year Question
A dipeptide, "x" on complete hydrolysis gives "y" and "z". "y" on treatment with aq. produces lactic acid. On the other hand "z" on heating gives the following cyclic molecule.
Based on the information given, the dipeptide X is:
- a
valine-glycine
- b✓
alanine-glycine
- c
valine-leucine
- d
alanine-alanine
alanine-glycine
Step 1: Finding 'y' — Alanine upon treatment with nitrous acid yields lactic acid (). Thus, 'y' is alanine.
Step 2: Finding 'z' — The cyclic structure shown in the image is a diketopiperazine formed from two units of glycine through dehydration. Thus, 'z' is glycine.
Step 3: Conclusion — Since the dipeptide 'x' hydrolyzes into alanine and glycine, 'x' must be alanine-glycine. Correct option is (b).
Remember: react with to form with the release of nitrogen gas.
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