JEE Main · 2019 · Shift-IImediumBIO-057

Fructose and glucose can be distinguished by:

Biomolecules · Class 12 · JEE Main Previous Year Question

Question

Fructose and glucose can be distinguished by:

Options
  1. a

    Fehling's test

  2. b

    Barfoed's test

  3. c

    Benedict's test

  4. d

    Seliwanoff's test

Correct Answerd

Seliwanoff's test

Detailed Solution

Step 1: Monosaccharide Classification — Glucose is an aldose (with an aldehyde group) and fructose is a ketose (with a keto group).

Step 2: Selecting the Test — Tests like Fehling’s\text{Fehling's} or Benedict’s\text{Benedict's} react with both reducing aldoses and ketoses. Seliwanoff’s test\text{Seliwanoff's test} is specifically used to distinguish them.

Step 3: Observation — In Seliwanoff’s test\text{Seliwanoff's test}, the keto-fructose reacts much faster under acidic conditions to give a cherry-red color, whereas aldo-glucose responds much more slowly.

Remember: Resorcinol in concentrated \ceHCl\ce{HCl} is the key constituent of Seliwanoff’s reagent\text{Seliwanoff's reagent}.

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