Number of stereo centers present in linear and cyclic structures of glucose are respectively.
Biomolecules · Class 12 · JEE Main Previous Year Question
Number of stereo centers present in linear and cyclic structures of glucose are respectively.
- a✓
4 and 5
- b
5 and 5
- c
4 and 4
- d
5 and 4
4 and 5
Step 1: Linear Glucose — In the open-chain form of glucose, there are four chiral centers located at carbons .
Step 2: Cyclic Glucose — When the ring closes, the carbonyl carbon () becomes a new chiral center (the anomeric carbon), creating and forms.
Step 3: Conclusion — Thus, the total count of stereocenters increases from four in the linear form to five in the cyclic form. Correct option is (a).
Key Point: The creation of a new chiral center during cyclization is the reason for the existence of anomers.
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