JEE Main · 2019 · Shift-IImediumBIO-061

Number of stereo centers present in linear and cyclic structures of glucose are respectively.

Biomolecules · Class 12 · JEE Main Previous Year Question

Question

Number of stereo centers present in linear and cyclic structures of glucose are respectively.

Options
  1. a

    4 and 5

  2. b

    5 and 5

  3. c

    4 and 4

  4. d

    5 and 4

Correct Answera

4 and 5

Detailed Solution

Step 1: Linear Glucose — In the open-chain form of glucose, there are four chiral centers located at carbons C2, C3, C4, and C5\text{C2, C3, C4, and C5}.

Step 2: Cyclic Glucose — When the ring closes, the carbonyl carbon (C1\text{C1}) becomes a new chiral center (the anomeric carbon), creating α\alpha and β\beta forms.

Step 3: Conclusion — Thus, the total count of stereocenters increases from four in the linear form to five in the cyclic form. Correct option is (a).

Key Point: The creation of a new chiral center during cyclization is the reason for the existence of anomers.

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Number of stereo centers present in linear and cyclic structures of glucose are respectively. (JEE Main 2019) | Canvas Classes