The formulas of A and B for the following reaction sequence are
Biomolecules · Class 12 · JEE Main Previous Year Question
The formulas of A and B for the following reaction sequence are
- a✓
- b
- c
- d
Step 1: Cyanohydrin Addition — Reaction of glucose () with adds one carbon atom, forming a cyanohydrin with the formula .
Step 2: Hydrolysis — Subsequent hydrolysis of the nitrile group () to a carboxylic acid () results in a hydroxy acid 'A' with the formula .
Step 3: Reduction — Treatment with and red phosphorus reduces the hydroxy groups to a straight-chain hydrocarbon. The resulting product is n-heptane or a related reduced structure. Matching 'A' as identified the correct option.
Key Point: This Kiliani-Fischer-like sequence confirms the presence of an aldehyde and a straight six-carbon chain in glucose.
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