JEE Main · 2019 · Shift-IImediumBIO-115

The peptide that gives positive ceric ammonium nitrate and carbylamine test is:

Biomolecules · Class 12 · JEE Main Previous Year Question

Question

The peptide that gives positive ceric ammonium nitrate and carbylamine test is:

Options
  1. a

    Lys-Asp

  2. b

    Ser-Lys

  3. c

    Gln-Asp

  4. d

    Asp-Gln

Correct Answerb

Ser-Lys

Detailed Solution

Step 1: Specificity of Tests — Ceric ammonium nitrate is a test for primary and secondary alcohols (producing a red color change).

Step 2: Carbylamine Test Purpose — The carbylamine test\text{carbylamine test} is specific for primary amines. In a peptide, the terminal amino group and side-chain amino groups are potential sites.

Step 3: Identifying the Peptide — Ser-Lys (Serine-Lysine) features an alcohol group on serine and a primary amino group (both terminal and side-chain). Correct option is (b).

Key Point: Lysine-Aspartate lacks the alcohol group, and Glutamine derivatives involve amides which do not react positively in these tests.

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