JEE Main · 2021 · Shift-IImediumBIO-045

Which of the following is correct structure of -anomer of maltose?

Biomolecules · Class 12 · JEE Main Previous Year Question

Question

Which of the following is correct structure of α\alpha-anomer of maltose? image

Options
  1. a

    Option a

  2. b

    Option b

  3. c

    Option c

  4. d

    Option d

Correct Answerd

Option d

Detailed Solution

Step 1: Maltose Composition — Maltose is a disaccharide made of two glucose units connected by an α-1,4-glycosidic\alpha\text{-1,4-glycosidic} bond.

Step 2: Anomeric Carbon State — The α\alpha-anomer of maltose refers to the free hemiacetal carbon (C1 of the second glucose unit) being in the α\alpha-position (OH pointing down in the Haworth projection).

Step 3: Identification — Analyzing the provided structures, (d) shows the correct α-1,4\alpha\text{-1,4} linkage between two glucose units and the correct α\alpha-configuration at the reducing end.

Key Point: Maltose exists in equilibrium between α\alpha and β\beta forms in solution due to mutarotation at the free hemiacetal carbon.

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Biomolecules) inside The Crucible, our adaptive practice platform.

Which of the following is correct structure of -anomer of maltose? (JEE Main 2021) | Canvas Classes