JEE Main · 2020 · Shift-IImediumBIO-047

Which one of the following statements is not true?

Biomolecules · Class 12 · JEE Main Previous Year Question

Question

Which one of the following statements is not true?

Options
  1. a

    Lactose contains α\alpha-glycosidic linkage between C1\text{C}_1 of galactose and C4\text{C}_4 of glucose.

  2. b

    Lactose is a reducing sugar and it gives Fehling’s\text{Fehling's} test.

  3. c

    On acid hydrolysis, lactose gives one molecule of D(+)-glucose\text{D(+)-glucose} and one molecule of D(+)-galactose\text{D(+)-galactose}.

  4. d

    Lactose \ce(C11H22O11)\ce{(C11H22O11)} is a disaccharide and it contains 88 hydroxyl groups.

Correct Answera

Lactose contains α\alpha-glycosidic linkage between C1\text{C}_1 of galactose and C4\text{C}_4 of glucose.

Detailed Solution

Step 1: Analyzing Disaccharide Linkages — Lactose is made of D-galactose\text{D-galactose} and D-glucose\text{D-glucose}. The glycosidic bond is formed between C1\text{C1} of galactose and C4\text{C4} of glucose.

Step 2: Stereochemical Correction — Importantly, this bond is the β\beta-anomeric form. Statement (a) claims it is an α\alpha-linkage, which is incorrect.

Step 3: Verifying Other Facts — Lactose is indeed a reducing sugar, yields glucose and galactose upon hydrolysis, and possesses eight hydroxyl (\ceOH-\ce{OH}) groups. Thus, only (a) is false.

Key Point: The β-1,4\beta\text{-1,4} linkage is a fundamental structural feature of milk sugar.

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Which one of the following statements is not true? (JEE Main 2020) | Canvas Classes