JEE Main · 2022 · Shift-IIeasyBOND-078

Consider the species CH4, NH4+ and BH4-. Choose the correct option with respect to these species:

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

Consider the species CH4\mathrm{CH_4}, NH4+\mathrm{NH_4^+} and BH4\mathrm{BH_4^-}. Choose the correct option with respect to these species:

Options
  1. a

    They are isoelectronic and only two have tetrahedral structures

  2. b

    They are isoelectronic and all have tetrahedral structures

  3. c

    Only two are isoelectronic and all have tetrahedral structures

  4. d

    Only two are isoelectronic and only two have tetrahedral structures

Correct Answerb

They are isoelectronic and all have tetrahedral structures

Detailed Solution

🧠 Check whether all three species are isoelectronic (same number of electrons) and determine the geometry of each.

| Species | Electrons | Structure | Geometry | |---|---|---|---| | \ceCH4\ce{CH4} | 6+4(1)=106 + 4(1) = 10 | 4 bonds + 0 LP | Tetrahedral | | \ceNH4+\ce{NH4+} | 7+4(1)1=107 + 4(1) - 1 = 10 | 4 bonds + 0 LP | Tetrahedral | | \ceBH4\ce{BH4-} | 5+4(1)+1=105 + 4(1) + 1 = 10 | 4 bonds + 0 LP | Tetrahedral |

All three have 10 electrons → isoelectronic. All three have 4 bond pairs and 0 lone pairs → all tetrahedral.

⚠️ Trap: Option (a) says "only two have tetrahedral structures" — incorrect since all three are tetrahedral. Option (c) says "only two are isoelectronic" — incorrect since all three have 10 electrons.

Answer: (b) Isoelectronic and all have tetrahedral structures\boxed{\text{Answer: (b) Isoelectronic and all have tetrahedral structures}}

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