JEE Main · 2024 · Shift-IIhardPERI-049

Consider elements A', B', C', D' where A' and B' are in Period 2, C' and D' in Period 3; A' and C' are in Group 1, B'…

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

Consider elements AA', BB', CC', DD' where AA' and BB' are in Period 2, CC' and DD' in Period 3; AA' and CC' are in Group 1, BB' and DD' are in Group 2. Which of the following is/are true?

A. Order of atomic radii: B<A<D<CB' < A' < D' < C' B. Order of metallic character: B<A<D<CB' < A' < D' < C' C. Size: D<C<B<AD' < C' < B' < A' D. Order of ionic radii: B2+<A+<D2+<C+B'^{2+} < A'^+ < D'^{2+} < C'^+

Options
  1. a

    A only

  2. b

    A, B and D only

  3. c

    A and B only

  4. d

    B, C and D only

Correct Answerb

A, B and D only

Detailed Solution

image 🧠 Decode the abstract labels first — A' = Li, B' = Be, C' = Na, D' = Mg The question gives Period and Group placements. A' (P2, G1) = Li, B' (P2, G2) = Be, C' (P3, G1) = Na, D' (P3, G2) = Mg. Translate before reasoning.

🗺️ Check each statement A — Atomic radii: B<A<D<CB' < A' < D' < C' → Be < Li < Mg < Na. Group 2 is smaller than Group 1 in the same period. Period 2 is smaller than Period 3 in the same group. Both rules satisfied. True.

B — Metallic character: same order B<A<D<CB' < A' < D' < C'. Metallic character tracks atomic size: a bigger atom loses its electron more easily. Same reasoning as A. True.

C — Size: D<C<B<AD' < C' < B' < A' → Mg < Na < Be < Li. This puts Period 3 atoms smaller than Period 2 atoms — that is wrong. Period 3 elements have an extra shell. False.

D — Ionic radii: B2+<A+<D2+<C+B'^{2+} < A'^+ < D'^{2+} < C'^+\ceBe2+<\ceLi+<\ceMg2+<\ceNa+\ce{Be^{2+}} < \ce{Li^+} < \ce{Mg^{2+}} < \ce{Na^+}. Standard values: \ceBe2+=45pm\ce{Be^{2+}} = 45\,\text{pm}, \ceLi+=76\ce{Li^+} = 76, \ceMg2+=72\ce{Mg^{2+}} = 72, \ceNa+=102\ce{Na^+} = 102. So 45<7672<10245 < 76 \approx 72 < 102. The order matches. True.

True statements: A, B, D.

⚠️ The trap Statement C looks similar to A but the order is reversed. Reading too fast, you might mark C as "the same trend". Always re-read each statement carefully before agreeing.

Answer: (b)\boxed{\text{Answer: (b)}}

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Consider elements A', B', C', D' where A' and B' are in Period 2, C' and D' in Period 3; A' and C'… (JEE Main 2024) | Canvas Classes