JEE Main · 2021 · Shift-IeasyPERI-030

The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

The ionic radii of K+^+, Na+^+, Al3+^{3+} and Mg2+^{2+} are in the order:

Options
  1. a

    \ceNa+\ce{Na^+} < \ceK+\ce{K^+} < \ceMg2+\ce{Mg^{2+}} < \ceAl3+\ce{Al^{3+}}

  2. b

    \ceAl3+\ce{Al^{3+}} < \ceMg2+\ce{Mg^{2+}} < \ceK+\ce{K^+} < \ceNa+\ce{Na^+}

  3. c

    \ceAl3+\ce{Al^{3+}} < \ceMg2+\ce{Mg^{2+}} < \ceNa+\ce{Na^+} < \ceK+\ce{K^+}

  4. d

    \ceK+\ce{K^+} < \ceAl3+\ce{Al^{3+}} < \ceMg2+\ce{Mg^{2+}} < \ceNa+\ce{Na^+}

Correct Answerc

\ceAl3+\ce{Al^{3+}} < \ceMg2+\ce{Mg^{2+}} < \ceNa+\ce{Na^+} < \ceK+\ce{K^+}

Detailed Solution

🧠 Three of these are isoelectronic, \ceK+\ce{K^+} is not — handle them in two steps \ceNa+\ce{Na^+}, \ceMg2+\ce{Mg^{2+}}, \ceAl3+\ce{Al^{3+}} all have 10 electrons. \ceK+\ce{K^+} has 18 electrons (one extra shell). So you cannot rank all four by Z alone. First rank the three 10-electron ions, then place \ceK+\ce{K^+}.

🗺️ Step 1 — the 10-electron trio Same electron cloud, ranked by Z: \ceNa+\ce{Na^+} (Z=11Z=11) → biggest of the three. \ceMg2+\ce{Mg^{2+}} (Z=12Z=12). \ceAl3+\ce{Al^{3+}} (Z=13Z=13) → smallest.

So \ceAl3+<\ceMg2+<\ceNa+\ce{Al^{3+}} < \ce{Mg^{2+}} < \ce{Na^+}.

Step 2 — fit \ceK+\ce{K^+} into the order \ceK+\ce{K^+} has the configuration of Argon — one shell more than \ceNa+\ce{Na^+}. An extra shell beats any difference in nuclear pull at this level. So \ceK+>\ceNa+\ce{K^+} > \ce{Na^+}.

Final order: \ceAl3+<\ceMg2+<\ceNa+<\ceK+\ce{Al^{3+}} < \ce{Mg^{2+}} < \ce{Na^+} < \ce{K^+}.

⚠️ The trap Option (b) puts \ceK+\ce{K^+} between \ceMg2+\ce{Mg^{2+}} and \ceNa+\ce{Na^+} as if all four were isoelectronic. They are not — \ceK+\ce{K^+} has 18 electrons. Always count electrons first. Mixing isoelectronic and non-isoelectronic ions in one question is a common JEE trap.

Answer: (c)\boxed{\text{Answer: (c)}}

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Classification of Elements & Periodicity) inside The Crucible, our adaptive practice platform.

The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order: (JEE Main 2021) | Canvas Classes