The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order:
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
The ionic radii of K, Na, Al and Mg are in the order:
- a
< < <
- b
< < <
- c✓
< < <
- d
< < <
< < <
🧠 Three of these are isoelectronic, is not — handle them in two steps , , all have 10 electrons. has 18 electrons (one extra shell). So you cannot rank all four by Z alone. First rank the three 10-electron ions, then place .
🗺️ Step 1 — the 10-electron trio Same electron cloud, ranked by Z: () → biggest of the three. (). () → smallest.
So .
Step 2 — fit into the order has the configuration of Argon — one shell more than . An extra shell beats any difference in nuclear pull at this level. So .
Final order: .
⚠️ The trap Option (b) puts between and as if all four were isoelectronic. They are not — has 18 electrons. Always count electrons first. Mixing isoelectronic and non-isoelectronic ions in one question is a common JEE trap.
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