JEE Main · 2024 · Shift-IIeasyDNF-006

Choose the correct option having all the elements with d10 electronic configuration from the following:

d & f-Block Elements · Class 12 · JEE Main Previous Year Question

Question

Choose the correct option having all the elements with d10d^{10} electronic configuration from the following:

Options
  1. a

    27Co,28Ni,26Fe,24Cr{}^{27}\text{Co},\, {}^{28}\text{Ni},\, {}^{26}\text{Fe},\, {}^{24}\text{Cr}

  2. b

    29Cu,30Zn,48Cd,47Ag{}^{29}\text{Cu},\, {}^{30}\text{Zn},\, {}^{48}\text{Cd},\, {}^{47}\text{Ag}

  3. c

    46Pd,28Ni,26Fe,24Cr{}^{46}\text{Pd},\, {}^{28}\text{Ni},\, {}^{26}\text{Fe},\, {}^{24}\text{Cr}

  4. d

    28Ni,24Cr,26Fe,29Cu{}^{28}\text{Ni},\, {}^{24}\text{Cr},\, {}^{26}\text{Fe},\, {}^{29}\text{Cu}

Correct Answerb

29Cu,30Zn,48Cd,47Ag{}^{29}\text{Cu},\, {}^{30}\text{Zn},\, {}^{48}\text{Cd},\, {}^{47}\text{Ag}

Detailed Solution

Checking Option (2) — all must have d10d^{10} in ground state:

| Element | Z | Ground State Config | d electrons | |---------|---|---------------------|-------------| | Cu | 29 | [Ar] 3d104s13d^{10} 4s^1 | 3d103d^{10} ✓ | | Zn | 30 | [Ar] 3d104s23d^{10} 4s^2 | 3d103d^{10} ✓ | | Cd | 48 | [Kr] 4d105s24d^{10} 5s^2 | 4d104d^{10} ✓ | | Ag | 47 | [Kr] 4d105s14d^{10} 5s^1 | 4d104d^{10} ✓ |

All four have completely filled d10d^{10} configuration. ✓

Other options fail: Co (3d73d^7), Ni (3d83d^8), Fe (3d63d^6), Cr (3d54s13d^5 4s^1) — none are d10d^{10}.

Answer: Option (2)

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