JEE Main · 2022 · Shift-IeasyDNF-012

In following pairs, the one in which both transition metal ions are colourless is:

d & f-Block Elements · Class 12 · JEE Main Previous Year Question

Question

In following pairs, the one in which both transition metal ions are colourless is:

Options
  1. a

    Sc3+,Zn2+\text{Sc}^{3+},\, \text{Zn}^{2+}

  2. b

    Ti4+,Cu2+\text{Ti}^{4+},\, \text{Cu}^{2+}

  3. c

    V2+,Ti3+\text{V}^{2+},\, \text{Ti}^{3+}

  4. d

    Zn2+,Mn2+\text{Zn}^{2+},\, \text{Mn}^{2+}

Correct Answera

Sc3+,Zn2+\text{Sc}^{3+},\, \text{Zn}^{2+}

Detailed Solution

Concept: Colour requires partially filled d orbitals (d1d^1d9d^9). d0d^0 and d10d^{10} ions are colourless.

| Ion | Config | Colour | |-----|--------|--------| | Sc3+\text{Sc}^{3+} | 3d03d^0 | Colourless ✓ | | Zn2+\text{Zn}^{2+} | 3d103d^{10} | Colourless ✓ | | Ti4+\text{Ti}^{4+} | 3d03d^0 | Colourless ✓ | | Cu2+\text{Cu}^{2+} | 3d93d^9 | Blue (coloured) ✗ | | V2+\text{V}^{2+} | 3d33d^3 | Violet ✗ | | Ti3+\text{Ti}^{3+} | 3d13d^1 | Purple ✗ | | Mn2+\text{Mn}^{2+} | 3d53d^5 | Faint pink ✗ |

Option (1): Both Sc3+\text{Sc}^{3+} (d0d^0) and Zn2+\text{Zn}^{2+} (d10d^{10}) are colourless. ✓

Answer: Option (1)

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In following pairs, the one in which both transition metal ions are colourless is: (JEE Main 2022) | Canvas Classes