JEE Main · 2022 · Shift-IeasyDNF-011

Which of the following has least tendency to liberate H2 from mineral acids?

d & f-Block Elements · Class 12 · JEE Main Previous Year Question

Question

Which of the following has least tendency to liberate H2\text{H}_2 from mineral acids?

Options
  1. a

    Cu

  2. b

    Mn

  3. c

    Ni

  4. d

    Zn

Correct Answera

Cu

Detailed Solution

Concept: Electrode Potential and H₂ Liberation

A metal liberates H2\text{H}_2 from mineral acids only if its E°M2+/ME°_{M^{2+}/M} is negative (lies above H in electrochemical series).

| Metal | E° (V) | Liberates H₂? | |-------|----------|----------------| | Zn | 0.76-0.76 | Yes ✓ | | Mn | 1.18-1.18 | Yes ✓ | | Ni | 0.25-0.25 | Yes ✓ | | Cu | +0.34+0.34 | No ✗ |

Cu has a positive E°, so it cannot displace H2\text{H}_2 from dilute mineral acids.

Answer: Option (1) — Cu

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Which of the following has least tendency to liberate H2 from mineral acids? (JEE Main 2022) | Canvas Classes