JEE Main · 2022 · Shift-IImediumEC-030

Given below are two statements: Statement I: For KI, molar conductivity increases steeply with dilution. Statement II:…

Electrochemistry · Class 12 · JEE Main Previous Year Question

Question

Given below are two statements:

Statement I: For KI, molar conductivity increases steeply with dilution. Statement II: For carbonic acid, molar conductivity increases slowly with dilution.

In the light of the above statements, choose the correct answer from the options given below:

Options
  1. a

    Statement I is correct and Statement II is incorrect

  2. b

    Both Statement I and Statement II are false

  3. c

    Statement I is true but Statement II is false

  4. d

    Statement I is false but Statement II is true

Correct Answerd

Statement I is false but Statement II is true

Detailed Solution

Strategy: Distinguish between the dilution behavior of strong and weak electrolytes. Identify the electrolyte type for \ceKI\ce{KI} and Carbonic acid.

Analysis:

  • KI: This is a strong electrolyte. According to the Debye-Hückel-Onsager equation, its molar conductivity increases slowly and linearly with the square root of concentration upon dilution. Statement I is false because it claims a "steep" increase.
  • Carbonic acid (\ceH2CO3\ce{H_2CO_3}): This is a weak electrolyte. At moderate concentrations, the increase is slow, but it rises steeply only at extremely high dilutions. Statement II is generally ac\cepted as true compared to KI.

Conclusion: Statement I is false, Statement II is true.

Answer: (d) Statement I is false but Statement II is true\boxed{\text{Answer: (d) Statement I is false but Statement II is true}}

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