JEE Main · 2020 · Shift-IIeasyEC-037

The variation of molar conductivity with concentration of an electrolyte (X) in aqueous solution is shown in the given…

Electrochemistry · Class 12 · JEE Main Previous Year Question

Question

The variation of molar conductivity with concentration of an electrolyte (X) in aqueous solution is shown in the given figure. image The electrolyte X is:

Options
  1. a

    HCl

  2. b

    NaCl

  3. c

    KNO3\mathrm{KNO_3}

  4. d

    CH3COOH\mathrm{CH_3COOH}

Correct Answerd

CH3COOH\mathrm{CH_3COOH}

Detailed Solution

Strategy: Interpret the shape of the Λm\Lambda_m vs C\sqrt{C} graph. Linear graphs are for strong electrolytes, while curved "steep" graphs are for weak electrolytes.

Analysis: The provided graph shows a curve that rises steeply at low concentrations and does not approach a finite inter\cept at zero concentration. This "J-shaped" curve is a hallmark of a weak electrolyte.

  • \ceHCl\ce{HCl}, \ceNaCl\ce{NaCl}, and \ceKNO3\ce{KNO3} are strong electrolytes.
  • \ceCH3COOH\ce{CH3COOH} (A\cetic acid) is a weak electrolyte.

Therefore, the electrolyte X is a\cetic acid.

Answer: (d) \ceCH3COOH\boxed{\text{Answer: (d) } \ce{CH3COOH}}

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