JEE Main · 2021 · Shift-ImediumGOC-088

Among the following structures, which resonating structure is least stable?

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

Among the following structures, which resonating structure is least stable? image

Options
  1. a

    Structure A

  2. b

    Structure B

  3. c

    Structure C

  4. d

    Structure D

Correct Answerb

Structure B

Detailed Solution

When we need to check for the least stable resonating structure, first we look at the octet completion. None of the structures given have complete octet, and all have charge separation. In such scenarios, simply applying the rules is not sufficient. You need to look closely at the structures, how charges are placed, and what makes a stable and unstable arrangement. Look at the structure B, where two positive charges are present on adjacent atoms, which creates a lot of repulsion. This is a very unlikely or unstable arrangement of atoms. This makes the option B the least stable resonating structure.

Answer: (b) Structure B\boxed{\text{Answer: (b) Structure B}}

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