JEE Main · 2024 · Shift-ImediumGOC-057

Match List-I with List-II (Electronic effects):

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

Match List-I with List-II (Electronic effects): image

Options
  1. a

    (A)-(IV), (B)-(III), (C)-(I), (D)-(II)

  2. b

    (A)-(III), (B)-(I), (C)-(II), (D)-(IV)

  3. c

    (A)-(II), (B)-(IV), (C)-(III), (D)-(I)

  4. d

    (A)-(I), (B)-(II), (C)-(IV), (D)-(III)

Correct Answera

(A)-(IV), (B)-(III), (C)-(I), (D)-(II)

Detailed Solution

Step 1: Matching Effects to Mechanisms

  • (A) Aniline resonance: Electrons move into the ring. This is +R+R effect. (A-IV)
  • (B) Cyclohexene + \ceH+\ce{H^+}: Double bond electrons migrate to the attacking reagent (\ceH+\ce{H^+}). This is +E+E effect. (B-III)
  • (C) Cyclohexene + \ceCN\ce{CN^-}: Double bond electrons move away from the attacking reagent (\ceCN\ce{CN^-}). This is E-E effect. (C-I)
  • (D) Nitrobenzene resonance: Electrons move toward the substituent. This is R-R effect. (D-II)

Step 2: Correct Match (A)-(IV), (B)-(III), (C)-(I), (D)-(II).

Answer: (a)\boxed{\text{Answer: (a)}}

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