Staggered and eclipsed conformers of ethane are:
General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question
Staggered and eclipsed conformers of ethane are:
- a
Mirror images
- b
Polymers
- c
Enantiomers
- d✓
Rotamers
Rotamers
Step 1: Define conformers
Conformers (or conformational isomers) are different spatial arrangements of a molecule that arise by rotation about a bond, without breaking any bonds.
Step 2: Classify the relationship between staggered and eclipsed ethane
- They are not mirror images (they are related by rotation, not reflection)
- They are not polymers (same molecular formula, not polymerized)
- They are not enantiomers (enantiomers are non-superimposable mirror images)
- They are conformational isomers = Rotamers
Rotamers are conformers that differ by rotation about a single bond.
Step 3: Verify
Ethane conformations:
- Staggered: dihedral angle = 60°, most stable
- Eclipsed: dihedral angle = 0°, least stable
- Both arise from rotation about the bond
Answer: Option (d) — Rotamers
Key Points to Remember:
- Conformers = same connectivity, differ only in rotation about bonds
- Rotamers = conformers interconvertible by bond rotation
- Enantiomers require non-superimposable mirror image relationship
- Conformers are NOT considered separate compounds
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