JEE Main · 2021 · Shift-IeasyGOC-493

Staggered and eclipsed conformers of ethane are:

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

Staggered and eclipsed conformers of ethane are:

Options
  1. a

    Mirror images

  2. b

    Polymers

  3. c

    Enantiomers

  4. d

    Rotamers

Correct Answerd

Rotamers

Detailed Solution

Step 1: Define conformers

Conformers (or conformational isomers) are different spatial arrangements of a molecule that arise by rotation about a σ\sigma bond, without breaking any bonds.

Step 2: Classify the relationship between staggered and eclipsed ethane

  • They are not mirror images (they are related by rotation, not reflection)
  • They are not polymers (same molecular formula, not polymerized)
  • They are not enantiomers (enantiomers are non-superimposable mirror images)
  • They are conformational isomers = Rotamers

Rotamers are conformers that differ by rotation about a single bond.

Step 3: Verify

Ethane conformations:

  • Staggered: dihedral angle = 60°, most stable
  • Eclipsed: dihedral angle = 0°, least stable
  • Both arise from rotation about the \ceCC\ce{C-C} bond

Answer: Option (d) — Rotamers

Key Points to Remember:

  • Conformers = same connectivity, differ only in rotation about σ\sigma bonds
  • Rotamers = conformers interconvertible by bond rotation
  • Enantiomers require non-superimposable mirror image relationship
  • Conformers are NOT considered separate compounds

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Staggered and eclipsed conformers of ethane are: (JEE Main 2021) | Canvas Classes