JEE Main · 2022 · Shift-IIeasyGOC-024

The correct decreasing order of priority of functional groups in naming an organic compound as per IUPAC system is:

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

The correct decreasing order of priority of functional groups in naming an organic compound as per IUPAC system is:

Options
  1. a

    -COOH > -CONH₂ > -COCl > -CHO

  2. b

    -SO₃H > -COCl > -CONH₂ > -CN

  3. c

    -COOR > -COCl > -NH₂ > C=O

  4. d

    -COOH > -COOR > -CONH₂ > -COCl

Correct Answerb

-SO₃H > -COCl > -CONH₂ > -CN

Detailed Solution

IUPAC Priority Series According to IUPAC, the priority of functional groups for suffix naming is: Carboxylic acid > Sulphonic acid > Esters > Acid Halides > Amides > Nitriles > Aldehydes > Ketones > Alcohols > Amines.

  • Sulphonic acid (\ceSO3H\ce{-SO_3H}) > Acid Chloride (\ceCOCl\ce{-COCl}) > Amide (\ceCONH2\ce{-CONH2}) > Cyanide (\ceCN\ce{-CN}). This perfectly follows the established priority order.

Step 3: Conclusion Option (b) is the correct decreasing order.

Answer: (b) - SO3H > -COCl > -CONH2 > -CN\boxed{\text{Answer: (b) - SO3H > -COCl > -CONH2 > -CN}}

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