JEE Main · 2019 · Shift-IeasyGOC-112

The correct IUPAC name of the following compound is

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

The correct IUPAC name of the following compound is image

Options
  1. a

    2-methyl-5-nitro-1-chlorobenzene

  2. b

    3-chloro-1-methyl-1-nitrobenzene

  3. c

    2-chloro-1-methyl-4-nitrobenzene

  4. d

    5-chloro-4-methyl-1-nitrobenzene

Correct Answerc

2-chloro-1-methyl-4-nitrobenzene

Detailed Solution

Step 1: Identifying Functional Groups and Priority

  • Substituents: Nitro (\ceNO2-\ce{NO2}), Chloro (\ceCl-\ce{Cl}), Methyl (\ceCH3-\ce{CH3}).
  • Benzene derivatives are named by giving lowest possible locants to substituents alphabetically.
  • Alphabetical priority: Chloro (C) > Methyl (M) > Nitro (N).
  • Step 2: Numbering Numbering as 1-chloro, 2-methyl, 4-nitro gives the set (1,2,4)(1, 2, 4). Any other numbering gives higher locant sets like (1,3,4)(1, 3, 4) or (1,2,5)(1, 2, 5).

Step 3: Conclusion Name: 2-chloro-1-methyl-4-nitrobenzene.

Answer: (c) 2-chloro-1-methyl-4-nitrobenzene\boxed{\text{Answer: (c) 2-chloro-1-methyl-4-nitrobenzene}}

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