JEE Main · 2023 · Shift-IIeasyGOC-022

The correct IUPAC nomenclature for the following compound is:

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

The correct IUPAC nomenclature for the following compound is: image

Options
  1. a

    5-Formyl-2-methylhexanoic acid

  2. b

    2-Methyl-5-oxohexanoic acid

  3. c

    2-Formyl-5-methylhexan-6-oic acid

  4. d

    5-Methyl-2-oxohexan-6-oic acid

Correct Answerb

2-Methyl-5-oxohexanoic acid

Detailed Solution

Step 1: Identify Principal Group and Longest Chain The principal functional group is the carboxylic acid (\ceCOOH\ce{-COOH}), so the carbon chain is numbered starting from this group. The longest chain containing the carbonyl group has 6 carbons → Hexanoic acid.

image Step 2: Numbering and Substituents

  • C1: \ceCOOH\ce{-COOH}
  • C2: Has a methyl group.
  • C5: The ketone oxygen is treated as a substituent called "oxo". Substituents: 2-methyl and 5-oxo.

Step 3: IUPAC Name Arrange substituents alphabetically: 2-Methyl-5-oxohexanoic acid.

Answer: (b) 2-Methyl-5-oxohexanoic acid\boxed{\text{Answer: (b) 2-Methyl-5-oxohexanoic acid}}

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