JEE Main · 2024 · Shift-ImediumGOC-058

What will be the decreasing order of basic strength of the following conjugate bases? OH⁻, RO⁻, CH₃COO⁻, Cl⁻

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

What will be the decreasing order of basic strength of the following conjugate bases?

OH⁻, RO⁻, CH₃COO⁻, Cl⁻

Options
  1. a

    Cl⁻ > OH⁻ > RO⁻ > CH₃COO⁻

  2. b

    RO⁻ > OH⁻ > CH₃COO⁻ > Cl⁻

  3. c

    OH⁻ > RO⁻ > CH₃COO⁻ > Cl⁻

  4. d

    Cl⁻ > RO⁻ > OH⁻ > CH₃COO⁻

Correct Answerb

RO⁻ > OH⁻ > CH₃COO⁻ > Cl⁻

Detailed Solution

Step 1: Comparing Basic Strength of Conjugate Bases Basic strength is inversely proportional to the acidic strength of the corresponding conjugate acid.

  • \ceROH\ce{ROH} (pKa16pK_a \sim 16) \rightarrow Conjugate base: \ceRO\ce{RO^-}
  • \ceH2O\ce{H2O} (pKa=15.7pK_a = 15.7) \rightarrow Conjugate base: \ceOH\ce{OH^-}
  • \ceCH3COOH\ce{CH3COOH} (pKa=4.76pK_a = 4.76) \rightarrow Conjugate base: \ceCH3COO\ce{CH3COO^-}
  • \ceHCl\ce{HCl} (pKa=7pK_a = -7) \rightarrow Conjugate base: \ceCl\ce{Cl^-}

Step 2: Conclusion Since acidity order is \ceHCl>AcOH>H2O>ROH\ce{HCl > AcOH > H2O > ROH}, the basicity order is: \ceRO>OH>CH3COO>Cl\ce{RO^- > OH^- > CH3COO^- > Cl-}.

Answer: (b)\boxed{\text{Answer: (b)}} image

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from General Organic Chemistry (GOC)) inside The Crucible, our adaptive practice platform.

What will be the decreasing order of basic strength of the following conjugate bases? OH⁻, RO⁻,… (JEE Main 2024) | Canvas Classes