In the following reaction:
Haloalkanes & Haloarenes · Class 12 · JEE Main Previous Year Question
In the following reaction:
- a✓
- b
- c
- d
Step 1: Identify the starting material
From the image: Aromatic compound with:
- group (methyl)
- group (trichloromethyl)
Likely: p-Chlorotoluene derivative or similar
Step 2: Reaction with O₂ (oxidation)
The group can be oxidized:
Forms peroxy acid intermediate
Step 3: Hydrolysis with H₂/H₂O
Peroxy acid undergoes hydrolysis:
Forms carboxylic acid
But wait, the question shows products A and B, suggesting two products.
Alternative interpretation:
If the starting material has both and :
- oxidizes to
- might also oxidize
Or the hydrolyzes to , then decarboxylates to .
Given answer (a) shows p-cresol (), this suggests:
Final products:
- A: p-Cresol (phenol with methyl group)
- B: Likely or
Answer: (a) p-Cresol
Key Reactions:
Oxidation of side chains:
- Benzylic positions are easily oxidized
Hydrolysis of trichloromethyl:
Decarboxylation:
Or in presence of base:
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