Major product P is:
Haloalkanes & Haloarenes · Class 12 · JEE Main Previous Year Question
Major product P is:
- a
- b✓
- c
- d
Step 1: Identify the starting material
From the image: Benzene ring with a 3-carbon side chain containing Br
Likely structure: (3-phenylpropyl bromide)
Or: (secondary benzylic bromide)
Step 2: Reaction with alcoholic KOH
Alcoholic KOH → E2 elimination → alkene
For 3-phenylpropyl bromide:
This gives allylbenzene (3-phenylpropene)
For secondary benzylic bromide:
This gives β-methylstyrene (prop-1-enylbenzene)
Step 3: Determine major product
Looking at option (b) which shows a conjugated diene, this suggests the starting material might have additional unsaturation or the product undergoes further elimination.
If the starting material is a dibromide or has a structure that allows conjugation:
For example, if starting with:
Elimination gives: (β-methylstyrene)
But option (b) shows a conjugated diene with the benzene ring, suggesting:
(phenylbutadiene)
This would require a longer carbon chain or specific starting material.
Given the answer is (b) and it shows conjugated system, the major product is likely:
Phenyl-conjugated diene (extended conjugation with benzene ring)
Answer: (b)
Key Points:
- Alcoholic KOH → E2 elimination
- Conjugated systems are more stable (thermodynamic product)
- Zaitsev's rule: more substituted alkene favored
- Extended conjugation (benzene + diene) provides extra stability
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