The major product of the following reaction is:
Haloalkanes & Haloarenes · Class 12 · JEE Main Previous Year Question
The major product of the following reaction is:
- a
- b
- c
- d✓
Step 1: Identify the starting material
From the image: Dibromide with phenyl group
Likely structure: (vicinal dibromide)
Step 2: Reaction with excess alcoholic KOH
Alcoholic KOH (excess) + heat → Double elimination
Vicinal dibromides undergo two E2 eliminations to form alkynes
Step 3: Mechanism
First elimination:
Forms vinyl bromide intermediate
Second elimination:
Forms alkyne
Step 4: Final product
Product: Phenylacetylene derivative (alkyne)
Structure:
Answer: (d) Alkyne structure
Key Concepts:
Vicinal dihalides → Alkynes:
General reaction:
Requirements:
- Excess strong base
- Heat
- Two equivalents of base needed
Mechanism:
- First E2: Forms vinyl halide
- Second E2: Forms alkyne
- Vinyl halides are less reactive but react under forcing conditions
Alternative with geminal dihalides:
Also forms alkynes via similar double elimination.
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