What is the IUPAC name of the following compound?
Haloalkanes & Haloarenes · Class 12 · JEE Main Previous Year Question
What is the IUPAC name of the following compound?
- a
3-Bromo-1,2-dimethylbut-1-ene
- b
3-Bromo-3-methyl-1,2-dimethylprop-1-ene
- c
2-Bromo-3-methylpent-3-ene
- d✓
4-Bromo-3-methylpent-2-ene
4-Bromo-3-methylpent-2-ene
Step 1: Identify the structure from the image
Structure:
Step 2: Find the longest carbon chain
Longest chain: 5 carbons → pentane
Step 3: Number the chain
Rule: Give the double bond the lowest number.
- Numbering from left: Double bond at C-2
- Numbering from right: Double bond at C-3
Choose left to right: C-2 has the double bond (lower number)
C1: CH3
C2: C (with CH3 substituent)
C3: C (double bond to C2)
C4: CH (with Br substituent)
C5: CH3
Step 4: Identify substituents
- Bromine at C-4: 4-bromo
- Methyl at C-3: 3-methyl
- Double bond between C-2 and C-3: pent-2-ene
Step 5: Write IUPAC name
Alphabetical order: bromo before methyl
4-Bromo-3-methylpent-2-ene
Answer: (d)
Key IUPAC Rules:
- Longest carbon chain with functional group
- Number to give functional group (double bond) lowest number
- Name substituents alphabetically
- Use hyphens between numbers and words, commas between numbers
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