JEE Main · 2022 · Shift-IImediumIEQ-011

Assertion: The amphoteric behaviour of water is explained by Lewis acid-base theory. Reason: Water acts as acid with…

Ionic Equilibrium · Class 11 · JEE Main Previous Year Question

Question

Assertion: The amphoteric behaviour of water is explained by Lewis acid-base theory.

Reason: Water acts as acid with NH3\mathrm{NH_3} and base with H2S\mathrm{H_2S}.

Choose the correct option:

Options
  1. a

    Both Assertion and Reason are true and Reason is the correct explanation of Assertion

  2. b

    Both Assertion and Reason are true but Reason is NOT the correct explanation of Assertion

  3. c

    Assertion is true but Reason is false

  4. d

    Assertion is false but Reason is true

Correct Answerd

Assertion is false but Reason is true

Detailed Solution

Step 1 — Evaluate Assertion: The amphoteric behaviour of water is explained by Bronsted-Lowry theory (proton donor/acceptor), NOT Lewis acid-base theory. Lewis theory deals with electron pair donation/acceptance. Assertion is FALSE

Step 2 — Evaluate Reason:

  • Water + NH3\mathrm{NH_3}: H2O+NH3OH+NH4+\mathrm{H_2O + NH_3 \rightleftharpoons OH^- + NH_4^+} \rightarrow water donates H+\mathrm{H^+} \rightarrow acts as acid
  • Water + H2S\mathrm{H_2S}: H2O+H2SH3O++HS\mathrm{H_2O + H_2S \rightleftharpoons H_3O^+ + HS^-} \rightarrow water accepts H+\mathrm{H^+} \rightarrow acts as baseReason is TRUE

Answer: Option (4) — Assertion false, Reason true

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Assertion: The amphoteric behaviour of water is explained by Lewis acid-base theory. Reason: Water… (JEE Main 2022) | Canvas Classes