JEE Main · 2022 · Shift-IIeasyIEQ-002

In base vs. acid titration, at the end point methyl orange is present as

Ionic Equilibrium · Class 11 · JEE Main Previous Year Question

Question

In base vs. acid titration, at the end point methyl orange is present as

Options
  1. a

    Quinonoid form

  2. b

    Heterocyclic form

  3. c

    Phenolic form

  4. d

    Benzenoid form

Correct Answera

Quinonoid form

Detailed Solution

Methyl orange is an acid-base indicator that changes colour based on pH.

Step 1 — Structure of methyl orange:

  • In acidic medium (pH < 3.1): exists as quinonoid form (red/pink colour)
  • In basic medium (pH > 4.4): exists as benzenoid form (yellow colour)

Step 2 — At end point of base vs. acid titration: In a base vs. acid titration (base in burette, acid in flask), the end point is reached when the solution becomes slightly acidic (pH ≈ 3.1-4.4 for methyl orange).

At the end point, the solution is acidic \rightarrow methyl orange is in the quinonoid form (red/orange).

Answer: Option (1) — Quinonoid form

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In base vs. acid titration, at the end point methyl orange is present as (JEE Main 2022) | Canvas Classes