JEE Main · 2019 · Shift-ImediumMOLE-195

25 g of an unknown hydrocarbon upon burning produces 88 g of CO2 and 9 g of H2O. This unknown hydrocarbon contains:

Some Basic Concepts (Mole Concept) · Class 11 · JEE Main Previous Year Question

Question

25 g of an unknown hydrocarbon upon burning produces 88 g of \ceCO2\ce{CO2} and 9 g of \ceH2O\ce{H2O}. This unknown hydrocarbon contains:

Options
  1. a

    24 g of carbon and 1 g of hydrogen

  2. b

    18 g of carbon and 7 g of hydrogen

  3. c

    22 g of carbon and 3 g of hydrogen

  4. d

    20 g of carbon and 5 g of hydrogen

Correct Answerd

20 g of carbon and 5 g of hydrogen

Detailed Solution

🧠 C from \ceCO2\ce{CO2}, H from \ceH2O\ce{H2O} Standard combustion analysis. Pull out the carbon mass from 88g\ceCO288\,\text{g}\,\ce{CO2} and the hydrogen mass from 9g\ceH2O9\,\text{g}\,\ce{H2O}. The numbers should add to 25g25\,\text{g} since the compound is only C and H.

🗺️ Step by step Mass of C =1244×88=24g= \frac{12}{44} \times 88 = 24\,\text{g}. Mass of H =218×9=1g= \frac{2}{18} \times 9 = 1\,\text{g}.

Check: 24+1=25g24 + 1 = 25\,\text{g}. The compound is fully accounted for.

So the answer is 24g24\,\text{g} C and 1g1\,\text{g} H.

⚠️ Common mistake Don't pick option (b) "18g18\,\text{g} C" — that comes from confusing the molar mass of water with the molar mass of carbon. Always use the 12/4412/44 ratio for carbon.

Answer: (a)\boxed{\text{Answer: (a)}}

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