JEE Main · 2022 · Shift-ImediumMOLE-180

Production of Fe in blast furnace: Fe3O4(s)+4CO(g)-3Fe(l)+4CO2(g). When 4.640\,kg of Fe3O4 and 2.520\,kg of CO are…

Some Basic Concepts (Mole Concept) · Class 11 · JEE Main Previous Year Question

Question

Production of Fe in blast furnace: FeX3OX4(s)X4+CO(g)3Fe(l)X4+COX2(g)\ce{Fe3O4(s)+4CO(g)->3Fe(l)+4CO2(g)}. When 4.640kg4.640\,\text{kg} of FeX3OX4\ce{Fe3O4} and 2.520kg2.520\,\text{kg} of CO are allowed to react, the amount of iron (in g) produced is: (MFe=56M_{\ce{Fe}}=56, MO=16M_O=16, MC=12M_C=12)

Options
  1. a

    14001400

  2. b

    22002200

  3. c

    33603360

  4. d

    42004200

Correct Answerc

33603360

Detailed Solution

🧠 Compare moles, not kilograms The reaction needs 11 mole of FeX3OX4\ce{Fe3O4} for every 44 moles of CO\ce{CO}. Convert both reactants to moles, find which one runs out first, then read the iron yield off the balanced equation.

🗺️ Step by step Molar mass of FeX3OX4=3(56)+4(16)=232g/mol\ce{Fe3O4} = 3(56) + 4(16) = 232\,\text{g/mol}. Moles of FeX3OX4=4640/232=20mol\ce{Fe3O4} = 4640 / 232 = 20\,\text{mol}. Moles of CO=2520/28=90mol\ce{CO} = 2520 / 28 = 90\,\text{mol}.

For 20mol20\,\text{mol} of oxide you need 4×20=80mol4 \times 20 = 80\,\text{mol} of CO. You have 9090, so CO\ce{CO} is in excess. FeX3OX4\ce{Fe3O4} is the limiting reagent.

Each FeX3OX4\ce{Fe3O4} gives 33 atoms of Fe: Moles Fe=20×3=60mol.\text{Moles Fe} = 20 \times 3 = 60\,\text{mol}. Mass Fe=60×56=3360g.\text{Mass Fe} = 60 \times 56 = 3360\,\text{g}.

Fast check 4640=20×2324640 = 20 \times 232 exactly. So you start with 2020 neat moles of oxide. Triple it for Fe atoms, multiply by 5656, done.

Answer: (c)\boxed{\text{Answer: (c)}}

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Production of Fe in blast furnace: Fe3O4(s)+4CO(g)-3Fe(l)+4CO2(g). When 4.640\,kg of Fe3O4 and… (JEE Main 2022) | Canvas Classes