JEE Main · 2022 · Shift-IeasyPB11-038

Choose the correct stability order of group 13 elements in their +1 oxidation state.

p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question

Question

Choose the correct stability order of group 13 elements in their +1 oxidation state.

Options
  1. a

    Al<Ga<In<Tl\mathrm{Al < Ga < In < Tl}

  2. b

    Tl<In<Ga<Al\mathrm{Tl < In < Ga < Al}

  3. c

    In<Tl<Ga<Al\mathrm{In < Tl < Ga < Al}

  4. d

    Ga<In<Al<Tl\mathrm{Ga < In < Al < Tl}

Correct Answera

Al<Ga<In<Tl\mathrm{Al < Ga < In < Tl}

Detailed Solution

Strategy: Rank Group 13 elements by stability of their +1 oxidation state.

Step 1: Inert Pair Effect The +1+1 oxidation state requires retaining the ns2ns^2 pair (inert pair). This tendency increases down the group due to the inert pair effect (relativistic contraction of nsns orbitals, poor shielding by d/f electrons).

Step 2: Stability Order

  • Al⁺: least stable (Al strongly prefers +3)
  • Ga⁺: slightly more stable than Al⁺ (but Ga still usually +3)
  • In⁺: more stable; In(I) compounds known
  • Tl⁺: most stable — Tl(I) is the predominant oxidation state

\ceAl<Ga<In<Tl\ce{Al < Ga < In < Tl}

Answer: (A) \ceAl<Ga<In<Tl\boxed{\text{Answer: (A) }\ce{Al < Ga < In < Tl}}

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