Choose the correct stability order of group 13 elements in their +1 oxidation state.
p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question
Choose the correct stability order of group 13 elements in their +1 oxidation state.
- a✓
- b
- c
- d
Strategy: Rank Group 13 elements by stability of their +1 oxidation state.
Step 1: Inert Pair Effect The oxidation state requires retaining the pair (inert pair). This tendency increases down the group due to the inert pair effect (relativistic contraction of orbitals, poor shielding by d/f electrons).
Step 2: Stability Order
- Al⁺: least stable (Al strongly prefers +3)
- Ga⁺: slightly more stable than Al⁺ (but Ga still usually +3)
- In⁺: more stable; In(I) compounds known
- Tl⁺: most stable — Tl(I) is the predominant oxidation state
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