JEE Main · 2024 · Shift-IIeasyPB12-001

The strongest reducing agent among the following is:

p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question

Question

The strongest reducing agent among the following is:

Options
  1. a

    NH3\mathrm{NH_3}

  2. b

    SbH3\mathrm{SbH_3}

  3. c

    BiH3\mathrm{BiH_3}

  4. d

    PH3\mathrm{PH_3}

Correct Answerc

BiH3\mathrm{BiH_3}

Detailed Solution

Strategy: Reducing power of group 15 hydrides depends on the MHM-H bond dissociation enthalpy.

Step 1: Thermal Stability As we move down the group from \ceN\ce{N} to \ceBi\ce{Bi}, the size of the central atom increases, leading to an increase in MHM-H bond length and a decrease in bond dissociation enthalpy.

Step 2: Reducing Power Lower bond dissociation enthalpy means the hydride can release hydrogen more easily. Thus, \ceBiH3\ce{BiH3} is the least stable and the strongest reducing agent in the group.

Answer: (Option) [c] \ceBiH3\boxed{\text{Answer: (Option) [c] $\ce{BiH3}$}}

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from p-Block Elements (Class 12)) inside The Crucible, our adaptive practice platform.

The strongest reducing agent among the following is: (JEE Main 2024) | Canvas Classes