JEE Main · 2023 · Shift-IImediumRDX-062

During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value of 3.…

Redox Reactions · Class 11 · JEE Main Previous Year Question

Question

During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs by value of 3. Identify which of the below medium will favour the reaction.

Options
  1. a

    Both aqueous acidic and neutral

  2. b

    Aqueous neutral

  3. c

    Both aqueous acidic and faintly alkaline

  4. d

    Aqueous acidic

Correct Answerb

Aqueous neutral

Detailed Solution

Step 1 — Oxidation state changes of Mn in different media:

| Medium | Reaction | Mn change | |---|---|---| | Acidic | MnO4Mn2+\mathrm{MnO_4^- \rightarrow Mn^{2+}} | +7+2+7 \rightarrow +2 (change = 5) | | Neutral | MnO4MnO2\mathrm{MnO_4^- \rightarrow MnO_2} | +7+4+7 \rightarrow +4 (change = 3) | | Alkaline | MnO4MnO42\mathrm{MnO_4^- \rightarrow MnO_4^{2-}} | +7+6+7 \rightarrow +6 (change = 1) |

Step 2 — Identify medium with change = 3:

In neutral (aqueous neutral) medium, Mn changes from +7+7 to +4+4 (a change of 3).

The reaction in neutral medium: 8MnO4+3S2O32+H2O8MnO2+6SO42+2OH\mathrm{8MnO_4^- + 3S_2O_3^{2-} + H_2O \rightarrow 8MnO_2 + 6SO_4^{2-} + 2OH^-}

Answer: Option (2) — Aqueous neutral

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During the reaction of permanganate with thiosulphate, the change in oxidation of manganese occurs… (JEE Main 2023) | Canvas Classes