JEE Main · 2022 · Shift-IImediumRDX-049

The neutralization occurs when 10 mL of 0.1 M acid 'A' is allowed to react with 30 mL of 0.05 M base M(OH)2. The…

Redox Reactions · Class 11 · JEE Main Previous Year Question

Question

The neutralization occurs when 10 mL of 0.1 M acid 'A' is allowed to react with 30 mL of 0.05 M base M(OH)2\mathrm{M(OH)_2}. The basicity of the acid 'A' is [M is a metal]

Options
  1. a

    1

  2. b

    2

  3. c

    3

  4. d

    4

Correct Answerc

3

Detailed Solution

Step 1 — At neutralisation, equivalents of acid = equivalents of base:

nacid×basicity=nbase×acidityn_{\mathrm{acid}} \times \text{basicity} = n_{\mathrm{base}} \times \text{acidity}

Step 2 — Moles of each: nacid=0.1×10×103=1×103 moln_{\mathrm{acid}} = 0.1 \times 10 \times 10^{-3} = 1 \times 10^{-3}\ \mathrm{mol} nbase=0.05×30×103=1.5×103 moln_{\mathrm{base}} = 0.05 \times 30 \times 10^{-3} = 1.5 \times 10^{-3}\ \mathrm{mol}

Step 3 — Acidity of M(OH)2\mathrm{M(OH)_2}: M(OH)2\mathrm{M(OH)_2} provides 2 OH\mathrm{OH^-} per formula unit → acidity = 2

Step 4 — Equivalents: nacid×basicity=nbase×2n_{\mathrm{acid}} \times \text{basicity} = n_{\mathrm{base}} \times 2 1×103×basicity=1.5×103×21 \times 10^{-3} \times \text{basicity} = 1.5 \times 10^{-3} \times 2 basicity=3×1031×103=3\text{basicity} = \frac{3 \times 10^{-3}}{1 \times 10^{-3}} = 3

Answer: Option (3) — 3

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