JEE Main · 2024 · Shift-IeasySALT-015

The compound that is white in color is

Salt Analysis · Class 12 · JEE Main Previous Year Question

Question

The compound that is white in color is

Options
  1. a

    ammonium sulphide

  2. b

    lead sulphate

  3. c

    lead iodide

  4. d

    ammonium arsinomolybdate

Correct Answerb

lead sulphate

Detailed Solution

Step 1: Analyze option (a)

Ammonium sulphide (\ce(NH4)2S\ce{(NH4)2S}) is practically known in solution form. Typically, "yellow ammonium sulphide" (which contains polysulphides \ce(NH4)2Sx\ce{(NH4)2S_x}) is commonly used in qualitative analysis. It is distinctively yellow.

Step 2: Analyze option (b)

Lead sulphate (\cePbSO4\ce{PbSO4}) is formed as an insoluble precipitate when sulfuric acid reacts with a lead salt (like lead nitrate). \cePb2++SO42>PbSO4v\ce{Pb^{2+} + SO4^{2-} -> PbSO4 v} This precipitate is white.

Step 3: Analyze option (c)

Lead iodide (\cePbI2\ce{PbI2}), formed upon reacting lead salts with a soluble iodide, is a characteristic bright yellow precipitate (Golden spangles).

Step 4: Analyze option (d)

Ammonium arsinomolybdate (\ce(NH4)3[As(Mo3O10)4]\ce{(NH4)3[As(Mo3O10)4]} or similar complexes) is the precipitate formed when an arsenate reacts with ammonium molybdate. It produces a characteristic canary yellow precipitate.

Step 5: Conclusion

The only compound out of the choices that is white is lead sulphate.

Key Points to Remember:

  • \cePbSO4\ce{PbSO4} and \cePbCl2\ce{PbCl2} are white precipitates of lead.
  • \cePbCrO4\ce{PbCrO4} and \cePbI2\ce{PbI2} are yellow precipitates.
  • \cePbS\ce{PbS} is a black precipitate.

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