JEE Main · 2023 · Shift-IImediumSOL-089

Evaluate the following statements for their correctness. A. The elevation in boiling point temperature of water will be…

Solutions · Class 12 · JEE Main Previous Year Question

Question

Evaluate the following statements for their correctness.

A. The elevation in boiling point temperature of water will be same for 0.1 M NaCl and 0.1 M urea.

B. Azeotropic mixture boil without change in their composition.

C. Osmosis always takes place from hypertonic to hypotonic solution.

D. The density of 32% H2SO4\mathrm{H_2SO_4} solution having molarity 4.09 M is approximately 1.26 g mL⁻¹.

E. A negatively charged sol is obtained when KI solution is added to silver nitrate solution.

Choose the correct answer from the options given below:

Options
  1. a

    B and D only

  2. b

    B, D and E only

  3. c

    A and C only

  4. d

    A, B and C only

Correct Answera

B and D only

Detailed Solution

Strategy:\n> Evaluate chemical statements by applying colligative property laws, concentration conversions, and definitions of solution types.\n\nEvaluation:\n- A. \ceNaCl\ce{NaCl} (i=2i=2) vs Urea (i=1i=1). At same MM, \ceNaCl\ce{NaCl} gives double the particles, so elevations differ. Incorrect.\n- B. Azeotropes have identical composition in liquid and vapour, so they boil at a constant temperature without changing composition. Correct.\n- C. Osmosis is solvent movement from low solute (Hypotonic) to high solute (Hypertonic). Incorrect.\n- D. Relation: M=frac10times%timesρMrM = \\frac{10 \\times \% \\times \rho}{M_r}. Let's verify: 4.09=frac10times32times1.2698    frac403.2984.114.09 = \\frac{10 \\times 32 \\times 1.26}{98} \implies \\frac{403.2}{98} \approx 4.11. It is \approximately correct. Correct.\n- E. When \ceKI\ce{KI} is added to excess \ceAgNO3\ce{AgNO3}, \ceAgI\ce{AgI} absorbs \ceAg+\ce{Ag+} ions to form a positive sol. Incorrect.\n\nBased on the options, B and D are the correct ones.\n\ntextAnswer:(1)\boxed{\\text{Answer: (1)}}

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