JEE Main · 2019 · Shift-ImediumSOL-109

The freezing point of a diluted milk sample is found to be −0.2°C, while it should have been −0.5°C for pure milk. How…

Solutions · Class 12 · JEE Main Previous Year Question

Question

The freezing point of a diluted milk sample is found to be −0.2°C, while it should have been −0.5°C for pure milk. How much water has been added to pure milk to make the diluted sample?

Options
  1. a

    1 cup of water to 2 cups of pure milk

  2. b

    3 cups of water to 2 cups of pure milk

  3. c

    1 cup of water to 3 cups of pure milk

  4. d

    2 cups of water to 3 cups of pure milk

Correct Answerb

3 cups of water to 2 cups of pure milk

Detailed Solution

Strategy:\n> Freezing point depression is proportional to the concentration of the solute. When milk is diluted with water, the concentration decreases, and the magnitude of the freezing point depression decreases proportionally.\n\nStep 1: Analyze the concentration ratio\n- Pure milk: ΔTf=0.5textK\Delta T_f = 0.5\\text{ K}\n- Diluted milk: ΔTf=0.2textK\Delta T_f = 0.2\\text{ K}\nfractextConcentrationtextdilutedtextConcentrationtextpure=frac0.20.5=frac25\\frac{\\text{Concentration}_{\\text{diluted}}}{\\text{Concentration}_{\\text{pure}}} = \\frac{0.2}{0.5} = \\frac{2}{5}\n\nStep 2: Determine the dilution ratio\nLet VmV_m be the volume of pure milk and VwV_w be the volume of added water.\nThe concentration is inversely proportional to volume:\nfracVmVm+Vw=frac25    5Vm=2Vm+2Vw\\frac{V_m}{V_m + V_w} = \\frac{2}{5} \implies 5 V_m = 2 V_m + 2 V_w\n3Vm=2Vw    fracVwVm=frac323 V_m = 2 V_w \implies \\frac{V_w}{V_m} = \\frac{3}{2}\nSo, 3 cups of water were added to every 2 cups of pure milk.\n\ntextAnswer:(2)\boxed{\\text{Answer: (2)}}

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