JEE Main · 2019 · Shift-IImediumTHERMO-048

5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its temperature becomes 200 K. If…

Thermodynamics · Class 11 · JEE Main Previous Year Question

Question

5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its temperature becomes 200 K.

If CV=28J K1mol1C_V = 28\,\text{J K}^{-1}\text{mol}^{-1} and R=8.0J K1mol1)R = 8.0\,\text{J K}^{-1}\text{mol}^{-1}), the values of ΔU\Delta U and Δ(pV)\Delta(pV) for this process are:

Options
  1. a

    ΔU=14J;Δ(pV)=0.8J\Delta U=14\,\text{J};\Delta(pV)=0.8\,\text{J}

  2. b

    ΔU=14kJ;Δ(pV)=4kJ\Delta U=14\,\text{kJ};\Delta(pV)=4\,\text{kJ}

  3. c

    ΔU=14kJ;Δ(pV)=18kJ\Delta U=14\,\text{kJ};\Delta(pV)=18\,\text{kJ}

  4. d

    ΔU=2.8kJ;Δ(pV)=0.8kJ\Delta U=2.8\,\text{kJ};\Delta(pV)=0.8\,\text{kJ}

Correct Answerb

ΔU=14kJ;Δ(pV)=4kJ\Delta U=14\,\text{kJ};\Delta(pV)=4\,\text{kJ}

Detailed Solution

🧠 ΔU=nCvΔT\Delta U = nC_v\Delta T and Δ(pV)=nRΔT\Delta(pV) = nR\Delta T — two separate formulas For any ideal gas process: ΔU\Delta U uses CvC_v; Δ(pV)=Δ(nRT)=nRΔT\Delta(pV) = \Delta(nRT) = nR\Delta T.

🗺️ Calculation n=5 moln = 5\text{ mol}, Cv=28 J K1mol1C_v = 28\text{ J K}^{-1}\text{mol}^{-1}, R=8.0 J K1mol1R = 8.0\text{ J K}^{-1}\text{mol}^{-1}, ΔT=200100=100 K\Delta T = 200 - 100 = 100\text{ K}

ΔU=nCvΔT=5×28×100=14000 J=14 kJ\Delta U = nC_v\Delta T = 5 \times 28 \times 100 = 14000\text{ J} = 14\text{ kJ}

Δ(pV)=nRΔT=5×8.0×100=4000 J=4 kJ\Delta(pV) = nR\Delta T = 5 \times 8.0 \times 100 = 4000\text{ J} = 4\text{ kJ}

Check: ΔH=ΔU+Δ(pV)=14+4=18 kJ\Delta H = \Delta U + \Delta(pV) = 14 + 4 = 18\text{ kJ}

⚠️ Trap: Don't add Δ(pV)\Delta(pV) to ΔU\Delta U when calculating Δ(pV)\Delta(pV) itself. They are separate quantities; Δ(pV)\Delta(pV) uses RR, not CpC_p.

Answer: (b)\boxed{\text{Answer: (b)}}

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