The enthalpy change for the adsorption process and micelle formation respectively are:
Thermodynamics · Class 11 · JEE Main Previous Year Question
The enthalpy change for the adsorption process and micelle formation respectively are:
- a
and
- b
and
- c✓
and
- d
and
and
🧠 Adsorption is exothermic; micelle formation is endothermic but entropy-driven Two processes, two opposite signs:
Adsorption: gas/solute molecules lose kinetic freedom and bond to a surface → energy is released → (exothermic). ✓
Micelle formation: surfactant tails cluster together to escape the aqueous environment. The hydrophobic effect is primarily entropy-driven — the process actually has a slightly positive (endothermic). The large gain in entropy of the surrounding water molecules drives spontaneity. ✓
This matches option (c): and .
⚠️ Trap: Students expect both to be exothermic because both are "thermodynamically favourable." Micelle formation is spontaneous, but its enthalpy is positive — it's entropy that drives it.
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