JEE Main · 2019 · Shift-IImediumTHERMO-080

The standard reaction Gibbs energy for a chemical reaction at an absolute temperature T is given by G = A - BT, where A…

Thermodynamics · Class 11 · JEE Main Previous Year Question

Question

The standard reaction Gibbs energy for a chemical reaction at an absolute temperature TT is given by ΔG=ABT\Delta G^\circ = A - BT, where AA and BB are non-zero constants. Which of the following is true about this reaction?

Options
  1. a

    Exothermic if B<0B<0

  2. b

    Endothermic if A>0A>0

  3. c

    Endothermic if A<0A<0 and B>0B>0

  4. d

    Exothermic if A>0A>0 and B<0B<0

Correct Answerb

Endothermic if A>0A>0

Detailed Solution

🧠 Comparing ΔG=ABT\Delta G^\circ = A - BT with ΔG=ΔHTΔS\Delta G^\circ = \Delta H^\circ - T\Delta S^\circ: A=ΔHA = \Delta H^\circ, B=ΔSB = \Delta S^\circ The constant term AA equals ΔH\Delta H^\circ and the coefficient of TT equals ΔS\Delta S^\circ.

🗺️ Checking each option (a) "Exothermic if B<0B < 0": B=ΔSB = \Delta S^\circ, so B<0B < 0 means ΔS<0\Delta S^\circ < 0. That tells us nothing about whether ΔH\Delta H^\circ is negative. FALSE

(b) "Endothermic if A>0A > 0": A=ΔHA = \Delta H^\circ. If A>0A > 0, then ΔH>0\Delta H^\circ > 0 → endothermic. TRUE

(c) "Endothermic if A<0A < 0 and B>0B > 0": A<0A < 0ΔH<0\Delta H^\circ < 0 → exothermic, not endothermic. FALSE

(d) "Exothermic if A>0A > 0 and B<0B < 0": A>0A > 0ΔH>0\Delta H^\circ > 0 → endothermic, not exothermic. FALSE

⚠️ Trap: Students sometimes confuse AA and BB with ΔH\Delta H and ΔS\Delta S having the wrong sign. Match term by term: AA (constant) = ΔH\Delta H^\circ; BB (coefficient of TT) = ΔS\Delta S^\circ.

Answer: (b)\boxed{\text{Answer: (b)}}

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