The mixture which shows positive deviation from Raoult's law is

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🧠 Intermolecular Tug-of-War
Raoult's Law says that in an ideal solution, molecules of A and B like each other exactly as much as they like themselves. 
- Positive Deviation: Molecules of A and B "don't like each other." They prefer to be in the vapor state rather than being together in the liquid.
- Negative Deviation: Molecules of A and B "love each other." They stay in the liquid more than they would alone.

🗺️ Evaluating the Pairs
- (a) Benzene + Toluene: Nearly ideal (similar structures).

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