Questions/Electrochemistry/In the electrolysis ...
Electrolysis & Faraday's LawsElectrochemistry

In the electrolysis of aqueous H2SO4H_2SO_4, what product is formed at the anode at high current density? (Contrast this with the product at low current density)

Expert Answer

Peroxodisulphate (S2O82S_2O_8^{2-}), instead of O2O_2. At low current density (dilute acid), Water is oxidized to give O2O_2 gas, 2H2O(l)O2(g)+4H+(aq)+4e2H_2O(l) \rightarrow O_2(g) + 4H^+(aq) + 4e^-. JEE Pro-Tip: This reaction is the first step in the industrial manufacture of H2O2H_2O_2(Hydrogen Peroxide). TheS2O82S_2O_8^{2-}is hydrolyzed to giveH2O2H_2O_2

Master this topic with Flashcards

Use our Spaced Repetition flashcards to memorize Electrolysis & Faraday's Laws and ace your exams.

Start Practicing Now